Nitrous oxide emission mitigation during low-carbon source wastewater treatment: effect of external carbon source...

Nitrous oxide (N₂O) generated during biological nitrogen removal in wastewater treatment processes has contributed an important proportion to the global warming effect. To evaluate the possibility of N₂O emission mitigating by changing carbon source supply strategies, nitrogen transformation characteristics and N₂O emissions with methanol one-time dosing and step dosing were investigated. Two sets of laboratory-scale sequencing batch biofilm reactors (SBBRs) were conducted to treat real domestic wastewater with low carbon source. The results revealed that reactors with methanol step dosing showed a lower N₂O emission of 0.0402 ± 0.0016 mg/(L·h), together with a higher total nitrogen and ammonia nitrogen removal efficiencies of 83.30% ± 1.21 and 93.45% ± 1.20, respectively. While N₂O emission from conventional one-time dosing reactors was 0.0741 ± 0.0025 mg/(L·h), total nitrogen and ammonia nitrogen removal efficiencies were 75.71% ± 0.54 and 88.45% ± 0.59, respectively. The N₂O emission factor of SBBR was reduced from 6.26% ± 0.21 to 3.40% ± 0.14 with methanol step dosing. Moreover, nitrification rates in aerobic phases were reduced, while denitrification rates in anoxic phases were elevated. Hence, carbon source step dosing enhanced nitrogen removal and reduced N₂O emission compared with one-time dosing, which is a simply achievable strategy for N₂O emission reduction in highly automated systems like wastewater treatment plants.