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Controlling the Infrared Dielectric Function through Atomic-Scale Heterostructures.

Daniel C Ratchford1, Christopher J Winta2, Ioannis Chatzakis3

  • 1U.S. Naval Research Laboratory , Washington , D.C. 20375 , United States.

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|June 12, 2019
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Summary
This summary is machine-generated.

Researchers engineered surface phonon polaritons (SPhPs) by tuning optic phonon frequencies in AlN/GaN superlattices. This breakthrough enables custom infrared optics and devices by controlling material properties at the atomic scale.

Keywords:
infraredinterface phononoptic phononspolar semiconductorsecond harmonic generationsuperlatticesurface phonon polaritons

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Area of Science:

  • Nanophotonics and Materials Science
  • Exploration of surface phonon polaritons (SPhPs) in the infrared (IR) spectral region.

Background:

  • Surface phonon polaritons (SPhPs) are crucial for nanophotonics, but their properties are typically fixed by material choice.
  • The spectral positions of optic phonon frequencies dictate SPhP characteristics, limiting tunability.

Purpose of the Study:

  • To demonstrate the alteration of optic phonon frequencies using atomic-scale superlattices (SLs) of polar semiconductors.
  • To investigate the impact of layer thicknesses on phonon frequencies and vibrational modes in AlN/GaN SLs.
  • To explore the potential for designing distinct dielectric functions and tunable IR optics.

Main Methods:

  • Fabrication of atomic-scale AlN/GaN superlattices (SLs).
  • Utilized second harmonic generation (SHG) spectroscopy to analyze optic phonon frequencies.
  • Investigated the dependence of phonon frequencies on constituent layer thicknesses.

Main Results:

  • Demonstrated strong dependence of optic phonon frequencies on layer thicknesses in AlN/GaN SLs.
  • Observed new vibrational modes confined to layers and at interfaces.
  • AlN/GaN SLs exhibit multiple Reststrahlen bands with normal/extreme hyperbolic dispersion and tunable permittivities.

Conclusions:

  • Controlling optic phonons in SLs allows for the design of unique dielectric functions beyond constituent materials or effective medium approximations.
  • Atomic-scale SLs offer a pathway to engineer SPhP properties for tunable IR optics and multifunctional devices.
  • This research advances the development of user-defined, actively tunable infrared optics and sources.