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In-Situ Growth of Gadolinium Phthalocyaninato Sandwich Complexes on the Ag(111) Surface
José I Urgel1,2, David Écija1,3, Saranyan Vijayaraghavan1
1Physics Department E20, Technical University of Munich, James Franck Str. 1, D-85748, Garching, Germany.
Abstract:
We report a low-temperature scanning tunneling microscopy investigation of the in-situ growth of gadolinium phthalocyaninato complexes by combined deposition of free-base phthalocyanines and gadolinium atoms on a smooth Ag(111) substrate. A careful control of the stoichiometry allows the expression of a multilevel structurecomposed of irregularly distributed Gdx-1 (Pc)x complexes, x=2-5, thus paving new avenues for surface-confined columnar growth.
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