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Related Concept Videos

Generator Voltage Control01:21

Generator Voltage Control

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Generator voltage control is crucial for maintaining the stable operation of synchronous generators and wind turbines. In older models, a DC generator driven by the rotor delivers DC power to the rotor's field winding, and the power is transferred through slip rings and brushes. In the latest models, static or brushless exciters are used. Static exciters rectify AC power from the generator terminals and then transfer the DC power directly to the rotor. Brushless exciters, on the other hand, use...
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Bonding in Metals02:32

Bonding in Metals

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Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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Alkali Metals03:06

Alkali Metals

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Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Metal-Ligand Bonds02:51

Metal-Ligand Bonds

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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
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Properties of Transition Metals02:58

Properties of Transition Metals

29.7K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
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Related Experiment Video

Updated: Jan 23, 2026

Generation of Zerovalent Metal Core Nanoparticles Using n-2-aminoethyl-3-aminosilanetriol
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Controllable Wrinkling Patterns on Chitosan Microspheres Generated from Self-Assembling Metal Nanoparticles.

Xichao Liang1, Mengyue Gao1, Hongxia Xie1

  • 1College of Chemistry and Molecular Sciences , Wuhan University , Wuhan 430072 , China.

ACS Applied Materials & Interfaces
|June 13, 2019
PubMed
Summary

Researchers created wrinkled microspheres from natural chitosan and silver nanoparticles (Ag NPs). These novel 3D structures enhance surface-enhanced Raman spectroscopy (SERS) signals for advanced applications.

Keywords:
Ag self-assemblycontrollable wrinkling surfacesurface-enhanced Raman spectroscopyswelling and deswellingwrinkled microsphere

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Surface Chemistry

Background:

  • Micro/nanoscale surface wrinkles impart unique material properties.
  • Controllable wrinkle fabrication is crucial for advanced material design.
  • Natural polysaccharides offer sustainable building blocks for novel materials.

Purpose of the Study:

  • To develop a method for creating controllable surface wrinkled microspheres using natural polysaccharides.
  • To investigate the properties and potential applications of these wrinkled microspheres.

Main Methods:

  • Fabrication of chitosan microspheres (approx. 55 μm) in an alkali/urea aqueous solution.
  • Layer-by-layer (LBL) self-assembly of silver nanoparticles (Ag NPs, approx. 5 nm) onto swelled chitosan microspheres.
  • Controlled deswelling to induce wrinkling due to differential swelling behaviors between the Ag NP shell and chitosan core.

Main Results:

  • Successfully fabricated surface wrinkled microspheres with controllable wrinkling patterns (60–300 nm).
  • The wrinkled microspheres exhibit a hierarchically porous structure and hydrophobicity.
  • Demonstrated superior performance as 3D surface-enhanced Raman spectroscopy (SERS) substrates due to enhanced signal amplification.

Conclusions:

  • Chitosan and silver nanoparticles can be combined to create tunable 3D wrinkled microspheres.
  • The wrinkled topography significantly enhances SERS detection capabilities.
  • These microspheres hold promise for miniature 3D devices and diverse technological applications.