Effect of residual chemicals on wormlike micelles assembled from a C₂₂-tailed cationic surfactant

Ultra-long-chain surfactants, particularly C₂₂-tailed ones, have attracted considerable attention because of their ease of self-assembly into wormlike micelles (WLMs). Commercial C₂₂-tailed surfactants often contain non-negligible amounts of chemical residues introduced during their production. Since the noncovalent driving force of wormlike self-assembly can be greatly affected by the composition, we hypothesized that the residual chemicals could play a significant role in tuning the micelle microstructure and macroscopic properties of the surfactants.

To confirm this hypothesis, a highly pure (>99%) C₂₂-tailed cationic surfactant, N-erucylamidopropyl-N,N,N-trimethylammonium iodide (EDAI) was synthesized, and various amounts of corresponding reactants (iodomethane or N-erucamidopropyl-N,N-dimethylamine) or solvents (acetone) commonly used in surfactant synthesis were introduced as residues. The impact of each individual residue on the macroscopic appearances, rheological properties, and micelle morphology of the surfactant solution were investigated.

Increasing the residue fraction in the EDAI solution resulted in an initial increase, followed by a dramatic drop in solution viscosity. This behavior was described in terms of micellar structural transformations based on analysis of cryo-TEM observations and surface tension measurements. These findings are of crucial importance in understanding the sophisticated behaviors of WLMs and will benefit the industrial preparation of ultra-long-chain surfactants for commercial use.