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A study on catalytic co-pyrolysis of kitchen waste with tire waste over ZSM-5 using TG-FTIR and Py-GC/MS
Jiawei Chen1, Xiaoqian Ma1, Zhaosheng Yu1
1Guangdong Province Key Laboratory of Efficient and Clean Energy Utilization, School of Electric Power, South China University of Technology, No. 381, Wushan Road, Tianhe District, Guangzhou 510640, China.
Abstract:
Co-pyrolysis characteristics of kitchen waste (KW) with tire waste (TW) were studied by TGA-FTIR and Py-GC/MS. The kinetic parameters were calculated by Ozawa-Flynn-Wall (OFW) and the Kissinger-Akahira-Sunose (KAS) methods. TGA-FTIR results indicated that CO2, CO, NO, NH3, SO2, CH and CC groups were the main gases released from the pyrolysis process, finding that a certain coupling synergistic interaction occurred between KW and TW. Co-pyrolysis of KW and TW displayed positive synergy in pyrolysis kinetics, especially at the ratio of 5:5 whose apparent activation energy declined 16.78% (by FWO) and 17.54% (by KAS). The Py-GC/MS results found that co-pyrolysis could increase the total peak area of volatile matters (10.92-15.34%). Moreover, co-pyrolysis could increase hydrocarbons (especially for olefins (13.25-37.42%)) and inhibit non-hydrocarbon compounds (about 63%) of volatile products. In brief, co-pyrolysis of KW and TW could be a potential way for improving quality of pyrolysis oil.
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