Effects of Mechanical Ball Milling Time on the Microstructure and Mechanical Properties of Mo₂NiB₂-Ni Cermets

Mo₂NiB₂-Ni cermets have been extensively investigated due to their outstanding properties. However, studies have not systematically examined the effect of the powder milling process on the cermets. In this study, Mo, Ni, and B raw powders were subjected to mechanical ball milling from 1 h to 15 h. XRD patterns of the milled powders confirmed that a new phase was not observed at milling times of 1 h to 15 h. With the increase in the mechanical ball milling time from 1 h to 11 h, raw powders were crushed to small fragments, in addition to a more uniform distribution, and with the increase in the mechanical ball milling time to greater than 11 h, milled powders changed slightly. Mo₂NiB₂-Ni cermets were fabricated by reaction boronizing sintering using the milled powders at different ball milling times. The milling time significantly affected the microstructure and mechanical properties of Mo₂NiB₂-Ni cermets. Moreover, the Mo₂NiB₂ cermet powder subjected to a milling time of 11 h exhibited the finest crystal size and the maximum volume fraction of the Mo₂NiB₂ hard phase. Furthermore, the cermets with a milling time of 11 h exhibited a maximum hardness and bending strength of 87.6 HRA and 1367.3 MPa, respectively.