2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant
Mekhman S Yusubov1, Natalia S Soldatova1, Pavel S Postnikov1
1The Tomsk Polytechnic University, 634050 Tomsk, Russia. yusubov@mail.ru.
Abstract:
A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.
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