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Finite-barrier corrections for multidimensional barriers in colored noise
Thomas Bartsch1, F Revuelta2,3, R M Benito2
1Centre for Nonlinear Mathematics and Applications, Department of Mathematical Sciences, Loughborough University, Loughborough LE11 3TU, England, United Kingdom.
Abstract:
The usual identification of reactive trajectories for the calculation of reaction rates requires very time-consuming simulations, particularly if the environment presents memory effects. In this paper, we develop a method that permits the identification of reactive trajectories in a system under the action of a stochastic colored driving. This method is based on the perturbative computation of the invariant structures that act as separatrices for reactivity. Furthermore, using this perturbative scheme, we have obtained a formally exact expression for the reaction rate in multidimensional systems coupled to colored noisy environments.
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