Mutualistic benefit in the self-sorted co-aggregates of peri-naphthoindigo and a 4-amino-1,8-naphthalimide derivative

Photoluminescence enhancement for all the members of a self-sorted co-aggregate was observed for the first time by successfully amalgamating AIEE and social self-sorting. Intermolecular H-bonding and π-π stacking were utilised to prepare several co-aggregates of peri-naphthoindigo (PNI) and a 4-amino-1,8-naphthalimide derivative dye, NH₂-NMI. In the heteromeric aggregates, photoluminescence intensities were increased by 28% for the imide and more than 400% for PNI. Due to spectral overlap between the emission of the imide and the absorption of PNI, energy transfer took place from the former to the latter. The heteromeric aggregates are dual emissive and the relative intensities of the emissions can easily be tuned by varying the stoichiometry of the dyes.