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Updated: Jan 23, 2026

Preparation of Silver-Palladium Alloyed Nanoparticles for Plasmonic Catalysis under Visible-Light Illumination
Published on: August 18, 2020
Synergistic palladium/enamine catalysis for asymmetric hydrocarbon functionalization of unactivated alkenes with
Chiyu Wei1, Xiaohan Ye1, Qingyu Xing1
1Department of Chemistry, University of South Florida, Tampa, FL 33620, USA. xmshi@usf.edu.
Abstract:
Synergistic palladium and enamine catalysis was explored to promote ketone addition to unactivated olefins. A secondary amine-based organocatalyst was identified as the optimal co-catalyst for the directed Pd-catalyzed alkene activation. Furthermore, asymmetric hydrocarbon functionalization of unactivated alkenes was also achieved with good to excellent yield (up to 96% yields) and stereoselectivity (up to 96% ee). This strategy presented an efficient approach to prepare α-branched ketone derivatives under mild conditions.
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