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Updated: Jan 23, 2026

Stable Aqueous Suspensions of Manganese Ferrite Clusters with Tunable Nanoscale Dimension and Composition
Published on: February 5, 2022
Hyperstable chromium(iii)/manganese(ii) bimetallic wheel clusters with visible photoactivity
Junxiang Zhang1, Jian Zhang2, Xuguang Liu3
1Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemistry, Hefei Science Center of CAS, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China. liuchem@ustc.edu.cn.
Abstract:
Two new chromium and manganese bimetallic nanoclusters, [Cr8-xMnx(OH)8-x(H2O)x(OOCC6H5)16, x = 1.11] (1) and [Cr4Mn4O4(OOCC6H5)12·3CH3CN·H2O] (2), have been synthesized in a one-pot solvothermal reaction in this work. Under visible irradiation, cluster 1 can produce an increased photocurrent and exhibits significant visible-light-driven photocatalytic activity for H2 evolution in an aqueous system. Most importantly, it exhibits ultrahigh stability in both acid and base aqueous solutions, making it an excellent synthon for preparing functional materials.
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