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Updated: Jan 22, 2026

Light-driven Enzymatic Decarboxylation
Published on: May 22, 2016
Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones
Chang Lian1, Guanglu Yue1, Jinshan Mao1
1Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry, College of Chemistry , Tianjin Normal University , Tianjin 300387 , P.R. China.
Abstract:
The visible-light-driven preparation of (hetero)aryl stannanes was carried out under both photocatalyst- and metal-free conditions via irradiation of arylazo sulfones in the presence of hexaalkyldistannanes. The reaction shows a high efficiency and a wide substrates scope. The resulting crude organotin derivatives can be directly employed in a Stille protocol.
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