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Updated: Jan 22, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Direct Observation of Li+ Ions Trapped in a Mg2+-Templated Metal-Organic Framework
Yi Han1,2, Kang Liu1, Michael A Sinnwell2
1Key Laboratory of Eco-chemical Engineering, College of Chemistry and Molecular Engineering , Qingdao University of Science and Technology , Qingdao , Shandong 266042 , P. R. China.
Abstract:
Herein we report the first example of a metal-organic framework (MOF) in which the location of Li+ ions trapped in the porous confinement can be unambiguously defined by single-crystal X-ray diffraction. Furthermore, the Li+-doped MOF shows significant enhancement in gas uptake as well as selective adsorption of CO2 over CH4.
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