Nearly monodispersed MoS₂ hierarchical architectures as superior anodes for electrochemical lithium-storage

In this paper, we developed a facile approach to synthesize well-dispersed 3D hierarchical porous MoS₂ architectures with assistance of polyacrylate and demonstrated their applications in lithium ion batteries (LIBs). It was confirmed that the uniform flower-like MoS₂ architectures were assembled by nanosheets comprising about ∼10 stacking layers. Polyacrylate was revealed to have a significant impact on controlling the formation of the uniform hierarchical flower-like architectures with desirable dispersity. It was believed that the polyacrylate could direct assembly of the MoS₂ nanosheets into hierarchical structures and could well stabilize and disperse MoS₂ architectures. Furthermore, a stable cycling capability (839 mAh g^-1 at 0.1 A g^-1 after 120 cycles) and superior rate ability of the MoS₂ architectures were achieved as anodes for LIBs. This remarkably enhanced electrochemical property could be ascribed to their beneficial structural features and surface-dominated capacitive contribution.