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Janus Nanostructures from ABC/B Triblock Terpolymer Blends.

Andrea Steinhaus1, Deepika Srivastva2, Arash Nikoubashman3

  • 1Physical Chemistry and Center for Nanointegration Duisburg-Essen (CENIDE), University Duisburg-Essen, 47057 Duisburg, Germany.

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|July 3, 2019
PubMed
Summary

Blending homopolymers with ABC triblock terpolymers allows continuous tuning of polybutadiene microphases. This enables the creation of diverse Janus nanostructures, including perforated Janus sheets, beyond previously known forms.

Keywords:
DPD simulationsJanus nanostructuresblock copolymersbulk morphologiespolymer blending

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Area of Science:

  • Polymer Science and Engineering
  • Materials Chemistry
  • Nanotechnology

Background:

  • ABC triblock terpolymers are key for synthesizing soft Janus nanoparticles (JNPs).
  • Previous JNP synthesis using these terpolymers yielded only spheres, cylinders, and sheets.
  • Controlling the geometry of the sandwiched microphase has been a limitation.

Purpose of the Study:

  • To explore continuous tuning of polybutadiene (PB) microphases in lamella morphologies.
  • To investigate the effect of blending polybutadiene homopolymer (hPB) into SBM triblock terpolymers.
  • To generate novel Janus nanostructures beyond spheres, cylinders, and sheets.

Main Methods:

  • Combined theoretical simulations and experimental synthesis.
  • Systematic variation of hPB volume fraction in polystyrene-block-polybutadiene-block-polymethylmethacrylate (SBM) terpolymers.
  • Morphological analysis of PB microdomains and subsequent crosslinking and redispersion.

Main Results:

  • Morphological transitions observed from PB-cylinders to perforated PB-lamellae and continuous PB-lamellae with increasing hPB.
  • Simulations confirmed homogeneous distribution of hPB within PB microdomains.
  • Successful generation of Janus cylinders, perforated Janus sheets, and Janus sheets.

Conclusions:

  • Blending homopolymers offers a versatile method for tuning microphase morphology in ABC triblock terpolymers.
  • This approach significantly expands the range of accessible Janus nanostructures.
  • Suggests potential for generating more complex Janus nanostructures than previously anticipated.