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Updated: Jan 22, 2026

Light-driven Enzymatic Decarboxylation
Published on: May 22, 2016
An earth-abundant system for light-driven CO2 reduction to CO using a pyridinophane iron catalyst
Yuto Sakaguchi1, Arnau Call2, Mihaela Cibian1
1Department of Chemistry, Faculty of Science, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan. ksakai@chem.kyushu-univ.jp.
Abstract:
Herein we report an earth-abundant photocatalytic system for CO2 reduction to CO based on an iron catalyst combined with a CuI photosensitizer. Under visible light irradiation CO is produced as the main product (TONCO = 565, TOFmaxCO = 114 h-1) with a high selectivity over H2 production (SelCO2 = 84%).
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