Electric-Field-Mediated Reversible Transformation between Supramolecular Networks and Covalent Organic Frameworks
Zhen-Feng Cai1, Gaolei Zhan1, Lakshya Daukiya1
1Department of Chemistry, Division of Molecular Imaging and Photonics , KU Leuven , Celestijnenlaan 200F , B-3001 Leuven , Belgium.
Abstract:
By using an oriented electric field in a scanning tunneling microscope, one can locally control the condensation of boronic acids at the liquid/solid interface. The phase transition between self-assembled molecular networks and covalent organic frameworks is controlled by changing the polarity of the applied bias. The electric-field-induced phase transformation is reversible under ambient conditions.
Related Concept Videos
Network Covalent Solids
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
Electric Field
In the new picture, imagine that the first charge sets up an electric field independent of all other charges in the universe. When another charge comes in its vicinity, the second charge experiences an electric force depending on the electric field at that point. The source charge does not...
Determining Electric Field From Electric Potential
In general, regardless of whether the electric field is uniform, it points in the direction of decreasing potential because the force on a positive...
Finding Electric Potential From Electric Field
Covalent Bonds
Electric Field Inside a Conductor
Suppose a piece of metal is placed near a positive charge. The free electrons in the metal are attracted to the external positive charge and migrate freely toward that region. This region then...


