A dual borohydride (Li and Na borohydride) catalyst/additive together with intermetallic FeTi for the optimization of...

The present study deals with the material tailoring of Mg(NH₂)₂-2LiH through dual borohydrides: the reactive LiBH₄ and the non-reactive NaBH₄. Furthermore, a pulverizer, as well as a catalyst FeTi, has been added in order to facilitate hydrogen sorption. Addition of LiBH₄ to LiNH₂ in a 1 : 3 molar ratio leads to the formation of Li₄(BH₄)(NH₂)₃ which also acts as a catalyst. However, the addition of NaBH₄ doesn't lead to any compound formation but shows a catalytic effect. The onset dehydrogenation temperature of thermally treated Mg(NH₂)₂-2LiH/(Li₄(BH₄)(NH₂)₃-NaBH₄) is 142 °C as against 196 °C for the basic material Mg(NH₂)₂-2LiH. However, with the FeTi catalyzed Mg(NH₂)₂-2LiH/(Li₄(BH₄)(NH₂)₃-NaBH₄, it has been reduced to 120 °C. This is better than other similar amide/hydride composites where it is 149 °C (when the basic material is catalyzed with LiBH₄). The FeTi catalyzed Mg(NH₂)₂-2LiH/(Li₄(BH₄)(NH₂)₃-NaBH₄ sample shows better de/re-hydrogenation kinetics as it desorbs 3.9 ± 0.04 wt% and absorbs nearly 4.1 ± 0.04 wt% both within 30 min at 170 °C (with the H₂ pressure being 0.1 MPa for desorption and 7 MPa for absorption). The eventual hydrogen storage capacity of Mg(NH₂)₂-2LiH/(Li₄(BH₄)(NH₂)₃-NaBH₄ together with FeTi has been found to be ∼5.0 wt%. To make the effect of catalysts intelligible, we have put forward in a schematic way the role of Li and Na borohydrides with FeTi for improving the hydrogen sorption properties of Mg(NH₂)₂-2LiH.