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Model-based evaluation of fouling mechanisms in powdered activated carbon/membrane bioreactor system
Juan Xiong1, Xingtao Zuo2, Shi Zhang2
1College of Science, Huazhong Agricultural University, Wuhan 430070, China.
Abstract:
Identifying the fouling degree of a membrane bioreactor (MBR) provides guidance on the determination of suitable membrane cleaning methods. There is still a lack of knowledge on the effects of powdered activated carbon (PAC) refresh ratio on the MBR fouling mechanism. Major fouling mechanisms of an MBR with constant flow rate at different PAC replenishment ratios were investigated by individual and combined mechanistic fouling models. The root mean square errors were employed to assess the prediction accuracy of the used fouling models. The combined models showed better prediction. The cake-complete model provided far better fits of the transmembrane pressure data, and provided good fits of other individual model predictions regardless of the PAC refreshment ratio. Fourier transform infrared spectroscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy confirmed that the cake layer clogging was the main fouling mechanism followed by complete blockage and standard plugging. The cake-complete model may be used to predict the fouling mechanisms in PAC/MBR systems.
Insights
Powdered activated carbon (PAC) replenishment ratio impacts membrane bioreactor (MBR) fouling. The cake-complete model accurately predicts fouling mechanisms, primarily cake layer clogging, in PAC/MBR systems.
Area of Science:
- Environmental Engineering
- Water Treatment Technologies
- Membrane Science
Background:
- Membrane bioreactors (MBR) are crucial for wastewater treatment.
- Understanding MBR fouling mechanisms is key to optimizing cleaning strategies.
- The influence of powdered activated carbon (PAC) on MBR fouling remains under-investigated.
Purpose of the Study:
- To investigate the effects of different PAC replenishment ratios on MBR fouling mechanisms.
- To evaluate the predictive accuracy of individual and combined mechanistic fouling models.
- To identify the dominant fouling mechanisms in PAC-enhanced MBR systems.
Main Methods:
- Utilized individual and combined mechanistic fouling models to analyze MBR performance at various PAC replenishment ratios.
- Employed root mean square errors to assess model prediction accuracy.
- Characterized the membrane surface using Fourier transform infrared spectroscopy, scanning electron microscopy, and energy dispersive X-ray spectroscopy.
Main Results:
- Combined fouling models demonstrated superior prediction accuracy compared to individual models.
- The cake-complete model provided the best fit for transmembrane pressure data across all PAC replenishment ratios.
- Cake layer clogging was identified as the primary fouling mechanism, followed by complete blockage and standard plugging.
Conclusions:
- The cake-complete model is effective for predicting fouling mechanisms in PAC/MBR systems.
- PAC replenishment ratio significantly influences MBR fouling behavior.
- Cake layer clogging is the predominant fouling issue in PAC-modified MBRs.
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