Evaluation of phosphate removal from aqueous solution using metal organic framework; isotherm, kinetic and...

Phosphate (PO₄ ^3-) is the main etiological factor of eutrophication in surface waters. Metal organic frameworks (MOFs) are novel hybrid materials with amazing structural properties that make them a prominent material for adsorption.

Zeolitic imidazolate framework 67 (ZIF-67), a water stable member of MOFs, with a truncated rhombic dodecahedron crystalline structure was synthesized in aqueous environment at room temperature and then characterized using XRD and SEM. PO₄ ^3- adsorption from synthetic solutions using ZIF-67 in batch mode were evaluated and a polynomial model (R²: 0.99, R² _adj: 0.98, LOF: 0.1433) developed using response surface methodology (RSM).

The highest PO₄ ^3- removal (99.2%) after model optimization obtained when ZIF-67 dose, pH and mixing time adjusted to 6.82, 832.4 mg/L and 39.95 min, respectively. The optimum PO₄ ^3- concentration in which highest PO₄ ^3- removal and lowest adsorbent utilization occurs, observed at 30 mg/L. PO₄ ^3- removal eclipsed significantly in the presence of carbonate. The equilibrium and kinetic models showed that PO₄ ^3- adsorbed in monolayer (q_max: 92.43 mg/g) and the sorption process controlled in the sorption stage. Adsorption was also more favorable at higher PO₄ ^3- concentration, according to the separation factor (K_R) graph. Thermodynamic parameters (minus signs of ∆G°, ∆H° of 0.179 KJ/mol and ∆S° of 44.91 KJ/mol.K) demonstrate the spontaneous, endothermic and physisorption nature of the process.

High adsorption capacity and adsorption rates, make ZIF-67 a promising adsorbent for PO₄ ^3- removal from aqueous environment.