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A sterically congested 1,2-diphosphino-1'-boryl-ferrocene: synthesis, characterization and coordination to platinum
Emmanuel Lerayer1, Patrice Renaut1, Julien Roger1
1Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB-UMR CNRS 6302), Université de Bourgogne Franche-Comté, 9 Avenue Alain Savary, 21078 Dijon, France. Jean-Cyrille.Hierso@u-bourgogne.fr.
Dalton Transactions (Cambridge, England : 2003)
|July 13, 2019
Abstract:
A new class of tritopic ferrocene-based ambiphilic compounds has been prepared by assembling diphosphino- and boryl-substituted cyclopentadienides at iron. The presence of five sterically demanding substituents on the ferrocene platform induces conformational constraints, as is apparent from XRD and NMR data, but does not prevent the chelating coordination to platinum. The Lewis acid moiety is pendant in both the free ligand and the platinum complex.