Rational Synthesis of Iron/Nitrogen-Doped Carbon Catalyst through a Spatial Isolation Strategy for Efficient Oxygen...

It remains challenging to rationally synthesize iron/nitrogen-doped carbon (Fe/N-C) catalysts with rich Fe-N_x atomic active sites for improved oxygen reduction reaction (ORR) electrocatalysis. A highly efficient Fe/N-C catalyst, which has been synthesized through a spatial isolation strategy, is reported. Derived from bioinspired polydopamine (PDA)-based hybrid microsphere precursors, it is a multifunctional carrier that loads atomically dispersed Fe³⁺ /Zn²⁺ ions through coordination interactions and N-rich melamine through electrostatic attraction and covalent bonding. The Zn²⁺ ions and melamine in the precursor efficiently isolate Fe³⁺ atoms upon pyrolysis to form rich Fe-N_x atomic active sites, and generate abundant micropores during high-temperature treatment; as a consequence, the resultant Fe-N/C catalyst contains rich catalytically active Fe-N_x sites and a hierarchical porous structure. The catalyst exhibits improved ORR activity that is superior to and close to that of Pt/C in alkaline and acidic solutions, respectively.