Near-infrared to violet triplet-triplet annihilation fluorescence upconversion of Os(ii) complexes by strong spin-forbidden transition
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Updated: Jan 22, 2026
Triplet Fusion Upconversion Nanocapsule Synthesis
Published on: September 7, 2022
Yaxiong Wei1, Min Zheng1, Lin Chen2
1Hefei National Laboratory for Physical Sciences at the Microscale, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui 230026, China. xzhou@ustc.edu.cn.
Abstract:
Three Os(ii) complexes were synthesized with ligands 2,2'-dipyridyl (dipy), 1,10-phenanthroline monohydrate (phen), and 4,7-diphenyl-1,10-phenanthroline (diphen), and applied as triplet photosensitizers for triplet-triplet annihilation (TTA) fluorescence upconversion. The strong spin-orbital coupling made direct spin-forbidden transition of S0-T1 feasible. Lifetimes of the lowest triplet state of these complexes were determined to be 107 ns, 373 ns, and 386 ns for Os-dipy, Os-phen, and Os-diphen, respectively, using nanosecond transient absorption spectra. From steady-state phosphorescence emission spectra, energies of the triplet states were derived to be 1.75 eV, 1.80 eV, and 1.74 eV for Os-dipy, Os-phen, and Os-diphen, respectively. Using these photosensitizers, strong upconverted fluorescence of the triplet acceptors, 9,10-diphenylanthracene (DPA), perylene, and 9,10-bis(phenethynyl) anthracene (BPEA), was observed in the visible to violet range. In particular, fluorescence emission with the largest anti-Stokes shift of 1.14 eV was observed for the Os-phen/DPA system, and the upconverted quantum yield was determined as 5.9% in deoxygenated dichloroethane. Additionally, upconversion was determined in air using mixtures of dichloroethane and DMSO solvents, and the maximal quantum yield was measured to be 4.5% for Os-phen/DPA.
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