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Updated: Jan 22, 2026

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
A huge novel polyoxometalate-based cluster Fe10P4W32 exhibiting prominent electrocatalytic activity for the oxygen
Wei Jiang1, Xiao-Mei Liu1, Jian Liu2
1College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, P. R. China. yanxu@njtech.edu.cn.
Abstract:
Two novel POM-based huge clusters modified by conjugated organic ligands (DAPSC), {Fe10P4W32} and {Fe8MoW18}, have been successfully isolated. Compound 1 consists of a novel huge inorganic building block {Fe10P4W32} and four organic groups DAPSC linked by ten iron ions and four sodium ions. The DAPSC ligands enhance the electric delocalization effects of polyoxoanions, leading to strengthening of the third-order nonlinear optical (NLO) responses of compounds 1-2. Additionally, the oxygen evolution reaction (OER) electrocatalytic activity and the magnetic properties of compound 1 have also been investigated.
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