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Th@C1(11)-C86: an actinide encapsulated in an unexpected C86 fullerene cage
Yaofeng Wang1, Roser Morales-Martínez2, Wenting Cai3
1Laboratory of Advanced Optoelectronic Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, P. R. China. chenning@suda.edu.cn.
Abstract:
A novel actinide endohedral fullerene with an unexpected chiral cage, Th@C1(11)-C86, was synthesized and characterized. DFT calculations suggest that this low symmetry cage was favoured as a consequence of the strong interaction between Th and the cage, which makes the predictions by the ionic model less reliable for these endohedral mono-metallofullerenes.
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