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Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond
Tadashi Yamaguchi1, Kohei Yoshiya1
1Department of Chemistry and Biochemistry, School of Advanced Science and Engineering , Waseda University , Tokyo 169-8555 , Japan.
Abstract:
New type isomers that differ in metal-metal bond type are isolated. One is the Pt-Hg-Pt complex, which has two metal-metal covalent bonds, Pt-Hg = 2.5459(8) and 2.5483(7) Å, and the other is the Pt→Hg-Pt complex, which has one metal-metal covalent bond, Pt-Hg = 2.5744(6) Å, and one metal-metal dative bond, Pt→Hg = 2.6635(7) Å.
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