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Excavated cubic platinum-iridium alloy nanocrystals with high-index facets as highly efficient electrocatalysts in N2
Yu-Jie Mao1, Lu Wei2, Xin-Sheng Zhao2
1School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China. lwei057@jsnu.edu.cn and State Key Lab of PCOSS, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China. sgsun@xmu.edu.cn.
Abstract:
Excavated cubic Pt93Ir7 alloy nanocrystals enclosed by high-index {710} facets exhibit excellent electrocatalytic properties for the nitrogen reduction reaction (NRR) with a high faradaic efficiency (40.8%) and NH3 production rate (28 μg h-1 cm-2). The presence of Ir on the Pt stepped surface suppresses the hydrogen evolution reaction (HER) and accelerates the NRR.
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