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Torsional chirality generation based on cyclic oligomers constructed from an odd number of pyrenes
Ryo Kurosaki1, Mitsuharu Suzuki2, Hironobu Hayashi1
1Division of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama-cho, Ikoma, Nara 630-0192, Japan. aratani@ms.naist.jp hyamada@ms.naist.jp.
Abstract:
A Ni(0)-mediated coupling reaction of a 1,8-dibromopyrene gave a series of cyclic pyrene oligomers CPn up to nonadecamer. CP5 and CP7 represent a unique class of asymmetric compounds with no stereogenic chiral centers in terms of their global chirality, which are achieved because of an odd number of pyrenes.
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