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Crystallization Behavior and Properties of Glass Fiber Reinforced Polypropylene Composites
Yuming Wang1,2, Lihong Cheng1, Xiaoqian Cui1
1Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China.
Abstract:
Glass fiber with different content and different kinds of compatibilizers were used to prepare glass fiber-reinforced polypropylene (GFRP) composites. β-nucleating agent with different content was used to prepare β-polypropylene (PP), after which the toughness, crystallization ability and heat resistance were all enhanced. Differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD) showed that the crystallite degree and crystallization ability were all greatly improved and β-PP was in dominant position. At last, both β-nucleating agent and glass fiber were used to modify the PP composites (β-GFRP). The formation of β-form PP made the matrix softer, which was beneficial for energy absorption and enhancement of toughness. The tensile strength, flexural strength and flexural modulus were improved dramatically, which were attributed to the coeffect of framework structure of GF and β-form PP.
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