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Multi-time formulation of Matsubara dynamics
Kenneth A Jung1, Pablo E Videla1, Victor S Batista1
1Department of Chemistry, Yale University, P.O. Box 208107, New Haven, Connecticut 06520-8107, USA.
This study generalizes Matsubara dynamics for multitime correlation functions. The new multitime Matsubara dynamics approximation serves as a benchmark for developing semiclassical methods in quantum dynamics.
Area of Science:
- Quantum Dynamics
- Statistical Mechanics
- Computational Physics
Background:
- Matsubara dynamics is a key theory for single-time correlation functions.
- Calculating multitime correlation functions in quantum systems is complex.
- Existing methods often lack generalizability for higher-order functions.
Purpose of the Study:
- To generalize Matsubara dynamics for multitime correlation functions.
- To establish a benchmark theory for Boltzmann-preserving semiclassical approximations.
- To explore the connection between path integral imaginary time-ordering and classical dynamics.
Main Methods:
- Extension of the Matsubara approximation to two-time correlation functions.
- Generalization to multitime fully symmetrized Kubo transformed correlation functions.
- Development of a multitime Matsubara dynamics approximation.
Main Results:
- The Matsubara approximation is applicable to two-time correlation functions.
- A multitime Matsubara dynamics approximation for multitime correlation functions is derived.
- A connection between imaginary time-ordering and classical dynamics is revealed.
Conclusions:
- The generalized multitime Matsubara dynamics provides a benchmark for future semiclassical approximations.
- This formulation highlights the link between quantum path integrals and classical dynamics.
- Further development is needed for practical applications due to a phase-term.
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