Dispersion analysis of the orthorhombic peptide single crystal Z-(Aib)3-L-Ala-OtBu
Sonja Höfer1, Albrecht Berg2, Hans Brückner3
1Leibnitz-Institut für Photonische Technologien e.V., Albert-Einstein-Straße 9, D-07745 Jena, Germany.
Abstract:
We present a dispersion analysis of the orthorhombic peptide single crystal Z-Aib-Aib-Aib-L-Ala-OtBu (N-benzyloxycarbonyl-α-aminoisobutyryl-α-aminoisobutyryl-α-aminoisobutyryl-L-alanine tert-butyl ester, C27H42N4O7), where Z is benzyloxycarbonyl and OtBu is the tert-butylester) in the MIR spectral region by means of adapted generalized dispersion analysis, employing the naturally grown crystal faces. Based on the results we identify the orientation of the crystal axes a, b, c within the sample, and supported by a stereographic projection of the crystal, we assign the individual axes. The gained dielectric tensor function and the oscillator parameters were confirmed by forward calculation of reflection spectra of different orientations. The orientation of the crystal axes was verified by a second stereographic projection with another crystal face in the center.
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