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Updated: Jan 21, 2026

Chemical Precipitation Method for the Synthesis of Nb2O5 Modified Bulk Nickel Catalysts with High Specific Surface Area
Published on: February 19, 2018
Photocatalytic hydrogen evolution on Si photocathodes modified with bis(thiosemicarbazonato)nickel(ii)/Nafion
Saumya Gulati1, Oleksandr Hietsoi, Caleb A Calvary
1Conn Center for Renewable Energy Research, University of Louisville, Louisville, Kentucky 40292, USA. joshua.spurgeon@louisville.edu.
Abstract:
The molecular catalyst diacetyl-bis(N-4-methyl-3-thiosemi-carbazonato)nickel(ii) (NiATSM) was integrated with Si for light-driven hydrogen evolution from water. Compared to an equivalent loading of Ni metal, the NiATSM/p-Si electrode performed better. Durability of the surface-bound catalyst under operation in acid was achieved without covalent attachment by using Nafion binding.
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