Liquid marbles and liquid plasticines with nanoparticle monolayers

Liquid marbles, as particle-covered macroscopic liquid drops in an air environment, have exhibited great value as self-standing liquid containers in various areas, such as material synthesis, chemical analysis, and cell culture. However, conventional liquid marbles obtained by the rolling-on-powder-bed method usually feature micron-sized or larger particle agglomerates, which harm marble transparency and fine control of marble shape and thus results in considerable limitations for marble applications. Recently, monolayer nanoparticle (NP) coverage has been achieved using a sol-gel film instead of a powder as the particle source. The NP monolayer structure can not only result in highly transparent liquid marbles with very smooth and symmetrical profiles, but can also lead to liquid entities with arbitrarily designable shapes, as called liquid plasticines. Monolayer NP-covered (mNPc) liquid marbles and plasticines have generated important results in both fundamental and practical applications, as ideal physical models or advanced self-standing containers, showing great advantages in some conditions over conventional powder-derived liquid marbles. In this review, the preparations and current applications of the two mNPc systems are summarized and perspectives on their advantages, unclear issues, and application extension are provided.