Water-guided synthesis of well-defined inorganic micro-/nanostructures

Water is one of the most commonplace solvents employed in wet chemical synthesis; however, it can sometimes play important roles such as an effective inducer or morphology-directing agent when introduced into a special reaction system, resulting in the formation of inorganic micro-/nanostructures with well-defined configurations. A better understanding of the key roles of water in the chemical synthesis will unlock a door to the design of many more novel single-component and hybrid nanocomposite architectures. Therefore, it is imperative to comprehensively review the topic of water-guided synthesis of well-defined micro-/nanostructures. Unfortunately, the significance of water has been underestimated and an in-depth study about the exact action of water in morphology-control is still lacking. In this review, we focus on the recent advances made in the development of the shape-controlled synthesis of inorganic micro-/nanostructures achieved by only adjusting the amount of water through some typical examples, including noble metals, metal oxides, perovskites, metal sulfides and oxysalts. In particular, the theory principles, synthesis strategies and growth mechanisms of the water-guided synthesis of well-defined inorganic micro-/nanostructures have been mainly highlighted. Finally, several current issues and challenges of this topic that need to be addressed in future investigations are briefly presented.