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Balancing Redox Equations02:58

Balancing Redox Equations

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Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or redox reactions. These important reactions are defined by changes in oxidation states for one or more reactant elements and include a subset of reactions involving the transfer of electrons between reactant species. Electrochemistry as a field has evolved to yield sufficient insights on the fundamental principles of redox chemistry and multiple...
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Redox Reactions01:24

Redox Reactions

58.4K
Oxidation-reduction or redox reactions involve the transfer of electrons from one molecule or atom to another. When an atom gains an electron, another atom must lose an electron, meaning oxidation and reduction must occur together. Since the redox occurs in pairs, the atom that gets oxidized is also called the reducing agent or reductant, and the atom that is reduced is also called the oxidizing agent or oxidant. A straightforward way to remember the definitions of oxidation and reduction is...
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Redox Reactions01:27

Redox Reactions

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Redox reactions are vital biochemical processes that underpin energy metabolism in cells. These reactions involve the transfer of electrons between molecules, occurring in tandem as oxidation and reduction. Oxidation refers to the loss of electrons, while reduction denotes their gain. This coupling ensures the seamless flow of electrons through metabolic pathways. For example, in bacterial metabolism, glucose undergoes oxidation to carbon dioxide, while oxygen is simultaneously reduced to...
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.5K
Structures of Solids02:22

Structures of Solids

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Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
17.5K
Network Covalent Solids02:18

Network Covalent Solids

16.1K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Related Experiment Video

Updated: Jan 21, 2026

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks

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Redox-Driven Reversible Gating of Solid-State Nanochannels.

Gregorio Laucirica1, Waldemar A Marmisollé1, María Eugenia Toimil-Molares2

  • 1Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Departamento de Química, Facultad de Ciencias Exactas , Universidad Nacional de La Plata (UNLP), CONICET , 64 y Diagonal 113 , 1900 La Plata , Argentina.

ACS Applied Materials & Interfaces
|July 24, 2019
PubMed
Summary

Researchers developed an electrochemically controlled nanofluidic diode using a redox polymer. This innovation allows tunable ion transport and rectification in nanofluidic devices, acting like ionic field-effect transistors.

Keywords:
electrochemical actuationionic diodesionic rectificationnanochannelsnanofluidic devicesnanofluidicspoly(vinylferrocene)redox polymerssolid-state nanopores

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Area of Science:

  • Nanotechnology
  • Electrochemistry
  • Materials Science

Background:

  • Nanofluidic devices offer precise control over fluid transport at the nanoscale.
  • Electrochemical control provides a versatile method for modulating device properties.

Purpose of the Study:

  • To design and demonstrate an electrochemically addressable nanofluidic diode.
  • To achieve tunable nanofluidic operations using redox gating.
  • To explore the potential of redox-active polymers in nanofluidic applications.

Main Methods:

  • Fabrication of an asymmetric gold-coated solid-state nanopore modified with poly(vinylferrocene) (PVFc).
  • Utilizing the redox state of PVFc to control surface charge density and ionic transport.
  • Applying electrochemical potentials to gate the nanofluidic channel.

Main Results:

  • The PVFc-modified nanochannel exhibited tunable rectification properties.
  • Electrochemical control accurately modulated surface charge density and ion transport.
  • The device demonstrated switchable iontronic behavior between ohmic and diode-like regimes, functioning as an ionic field-effect transistor.

Conclusions:

  • Redox-active polymers integrated into nanofluidic devices offer a simple and versatile platform for electrochemically addressable systems.
  • The developed nanofluidic diode allows for rapid, reversible modulation of ionic transport.
  • This technology holds promise for diverse nanofluidic applications requiring precise electrochemical control.