Where to find equilibrium constants?

Wolfgang Hummel1, Montserrat Filella2, Darren Rowland3

  • 1Laboratory for Waste Management, Paul Scherrer Institute, Forschungsstrasse 111, CH-5232 Villigen PSI, Switzerland.

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The equilibrium constant for a reaction is calculated from the equilibrium concentrations (or pressures) of its reactants and products. If these concentrations are known, the calculation simply involves their substitution into the Kc expression.
For example, gaseous nitrogen dioxide forms dinitrogen tetroxide according to this equation:
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Consider the oxidation of sulfur dioxide:
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The effect of an inert salt on the solubility of a sparingly soluble salt is known as the salt effect. The degree of the salt effect varies with the ionic strength of the solution, which in turn depends on the activity of the species in the solution. The activity is expressed as the product of concentration and the activity coefficient of the species.
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