Related Experiment Video
Updated: Jan 21, 2026

Pretreatment of Lignocellulosic Biomass with Low-cost Ionic Liquids
Published on: August 10, 2016
MIL-53(Al) as a Versatile Platform for Ionic-Liquid/MOF Composites to Enhance CO2 Selectivity over CH4 and N2
Safiyye Kavak1,2, H Mert Polat1,2, Harun Kulak3,2
1Department of Materials Science and Engineering, Koç University, Rumelifeneri Yolu, 34450 Sariyer, Istanbul, Turkey.
Abstract:
Five different imidazolium-based ionic liquids (ILs) were incorporated into a metal-organic framework (MOF), MIL-53(Al), to investigate the effect of IL incorporation on the CO2 separation performance of MIL-53(Al). CO2 , CH4 , and N2 adsorption isotherms of the IL/MIL-53(Al) composites and pristine MIL-53(Al) were measured to evaluate the effect of the ILs on the CO2 /CH4 and CO2 /N2 selectivities of the MOF. Of the composite materials that were tested, [BMIM][PF6 ]/MIL-53(Al) exhibited the largest increase in CO2 /CH4 selectivity, 2.8-times higher than that of pristine MIL-53(Al), whilst [BMIM][MeSO4 ]/MIL-53(Al) exhibited the largest increase in CO2 /N2 selectivity, 3.3-times higher than that of pristine MIL-53(Al). A comparison of the CO2 separation potentials of the IL/MOF composites showed that the [BMIM][BF4 ]- and [BMIM][PF6 ]-incorporated MIL-53(Al) composites both showed enhanced CO2 /N2 and CO2 /CH4 selectivities at pressures of 1-5 bar compared to composites of CuBTC and ZIF-8 with the same ILs. These results demonstrate that MIL-53(Al) is a versatile platform for IL/MOF composites and could help to guide the rational design of new composites for target gas-separation applications.
Related Concept Videos
Ionic Radii
Ionic Bonds
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
Molecular and Ionic Solids
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Solubility of Ionic Compounds
Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Ionic Compounds: Formulas and Nomenclature

