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Updated: Jan 21, 2026

Fabrication of Uniform Nanoscale Cavities via Silicon Direct Wafer Bonding
Published on: January 9, 2014
Reversible Sn-Sn Triple Bond Dissociation in a Distannyne: Support for Charge-Shift Bonding Character
Ting Yi Lai1, Lizhi Tao1, R David Britt1
1Department of Chemistry , University of California , One Shields Avenue , Davis , California 95616 , United States.
Abstract:
The tin-tin triple bond in the distannyne ArSnSnAr, Ar = C6H3-2,6(C6H3-2,6-iPr2)2, undergoes reversible cleavage in deuterated toluene to afford two :SṅAr radicals in solution as shown by 1H nuclear magnetic resonance and electron paramagnetic resonance spectroscopy. Variable temperature data afforded an enthalpy of dissociation of ΔHdiss = 17.2 ± 1.7 kcal mol-1 via van't Hoff analysis.
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