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PN-Containing Pyrene Derivatives: Synthesis, Structure, and Photophysical Properties
Chun-Lin Deng1, Jeremy P Bard1, Lev N Zakharov2
1Department of Chemistry & Biochemistry and the Materials Science Institute , University of Oregon , Eugene , Oregon 97403-1253 , United States.
Abstract:
A straightforward method for the preparation of non-K region fused phosphorus- and nitrogen-containing (PN)-heterocyclic pyrenes has been accomplished. Their structural, photophysical, and electrochemical properties have been fully investigated. The described compounds exhibit intriguing redox properties and show strong photoluminescence with a wide range of tunable emission colors, with λem ranging from blue at 459 nm to red at 622 nm in CH2Cl2 solution.
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