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Updated: Jan 21, 2026

Preparation of Silver-Palladium Alloyed Nanoparticles for Plasmonic Catalysis under Visible-Light Illumination
Published on: August 18, 2020
Cascade Alkynylation and Highly Selective Hydrogenation Catalyzed by Binaphthyl-Palladium Nanoparticles Accessing
Yun-Tao Xia1, Jin-Jin Wu1, Cheng-Yun Zhang1
1Jiangsu Key Laboratory of Pesticide Science and Department of Chemistry, College of Sciences , Nanjing Agricultural University , Nanjing 210095 , China.
Abstract:
A cascade alkynylation and selective hydrogenation catalyzed by covalent binaphthyl-stabilized palladium nanoparticles has been established, providing a novel and highly efficient methodology for accessing Z and Z,Z-selective phosphinyl [3]dendralenes with broad functional group tolerance and good yields. This strategy achieves the first cascade reactions of alkynylation and hydrogenation with chemoselectivity modulated by catalyst loading.
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