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Updated: Jan 21, 2026

Reactive Vapor Deposition of Conjugated Polymer Films on Arbitrary Substrates
Published on: January 17, 2018
β-Strand inspired bifacial π-conjugated polymers
Saikat Chaudhuri1, Manikandan Mohanan1, Andreas V Willems1
1Department of Chemistry , Institute for Soft Matter Synthesis and Metrology , Georgetown University , 3700 O st NW , Washington , D.C. 20057 , USA .
Abstract:
Access to diverse, relatively high molecular weight soluble linear polymers without pendant solubilizing chains is the key to solution state synthesis of structurally diverse nanoribbons of conjugated materials. However, realizing soluble 1D-π-conjugated polymers without pendant solubilizing chains is a daunting task. Herein, inspired from the polypeptide β-strand architecture, we have designed and developed novel bifacial π-conjugated polymers (M n: ca. 24 kDa) that are soluble (ca. 70 to >250 mM) despite the absence of pendant solubilizing chains. The impact of varying the bifacial monomer height on polymer solubility, optical properties, and interactions with small molecules is reported.
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