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Updated: Jan 21, 2026

Assembly, Tuning and Use of an Apertureless Near Field Infrared Microscope for Protein Imaging
Published on: November 25, 2009
Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster
Anton A Ivanov1, Clément Falaise2, David Landy3
1Institut Lavoisier de Versailles, CNRS, UVSQ, Université Paris-Saclay, Versailles, France. mohamed.haouas@uvsq.fr Emmanuel.cadot@uvsq.fr and Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, 630090, Russia and The Federal Research Center of Fundamental and Translational Medicine, Novosibirsk, 630117, Russia.
Abstract:
We report how only one electron transfer from the hydrophilic reduced cluster [{Re6Se8}(CN)6]4- induces both a dramatic increase of the host-guest affinity with γ-cyclodextrin and a drastic alteration of the supramolecular dynamics. This striking behaviour, underlined by its thermochemical fingerprint, indicates that the self-assembly process is driven by a chaotropic effect.
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