Ultra-small Pd nanoparticles derived from a supramolecular assembly for enhanced electrochemical reduction of CO2 to CO
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Updated: Jan 21, 2026

Liquid-cell Transmission Electron Microscopy for Tracking Self-assembly of Nanoparticles
Published on: October 16, 2017
Ruru Chen1, Minna Cao, Weiguang Yang
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China. mncao@fjirsm.ac.cn hongfangli@fjirsm.ac.cn rcao@fjirsm.ac.cn.
Abstract:
Ultra-small Pd nanoparticles were successfully prepared through reduction of a supramolecular assembly formed between the macrocyclic decamethylcucurbit[5]uril (Me10CB[5]) and [PdCl4]2- anions via H-bonds. The final Pd NPs exhibit excellent activity and stability toward the electrochemical reduction of CO2 to CO. This work provides a new strategy for the preparation of nanocatalysts.
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