CO₂ Reduction of Hybrid Cu₂ O-Cu/Gas Diffusion Layer Electrodes and their Integration in a Cu-based...

Cu₂ O/gas diffusion layer (GDL) electrodes prepared by electrodeposition were studied for the electrocatalytic reduction of CO₂ . The designed electrode was also tested in solar-light-induced CO₂ conversion in combination with a CuO/NtTiO₂ photoanode using a compact photoelectrocatalytic (PEC) cell. Both PEC cell electrodes were prepared using non-critical raw materials and low cost, easily scalable procedures. In the PEC experiments, a total carbon faradaic selectivity of about 90 % to formate and about 75 % to acetate was obtained after 24 h of operations without application of potential/current or using sacrificial agents. In electrocatalytic tests of CO₂ reduction at -1.5 V, the same electrode yielded high total faradaic selectivity (>95 %) but formed selectively formate (about 80 % selectivity) rather than acetate. The in situ transformation of the Cu₂ O/GDL electrode leads to the formation of a hybrid Cu₂ O-Cu/GDL system. Cyclic voltammetry data indicate that the potential and the presence of CO₂ (not only of HCO₃ ^- species) are both important elements in this transformation. Data also indicate that the surface concentration of CO₂ (or of its products of transformation) on the electrode is an important factor to determine performance in the conversion of CO₂ .