Related Experiment Video
Updated: Jan 21, 2026

Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites
Published on: September 19, 2020
Polyhedral Oligomeric Silsesquioxane Hybrid Polymers: Well-Defined Architectural Design and Potential Functional
Fang Chen1,2, Feng Lin2, Qi Zhang2
1Research & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen, 518097, P. R. China.
Abstract:
Polyhedral oligomeric silsesquioxane (POSS)-hybrid polymers have been successfully employed as functional inorganic-organic hybrid materials for various applications due to their well-determined structures. The past 6 years has witnessed growing interest in the rational design and synthetic approaches for POSS-hybrid polymers, driven by the adoption of controlled living radial polymerization and click chemistry. This review addresses developments in the precise manipulation of POSS building blocks via atom transfer radical polymerization, reversible addition-fragmentation chain transfer, and click chemistry. Not only are the structures of POSS-hybrid polymers tunable in terms of chemical composition, molecular weight, and polydispersity, but they are also controllable in sequential and hierarchical chain topology. Finally, some representative cutting-edge applications of POSS-hybrid polymers, including biomedical and energy-related materials, fabrication of nanostructures, and functional surface coating materials, are highlighted.
Related Concept Videos
Polymer Classification: Architecture
Polymers: Defining Molecular Weight
The number average molecular weight (Mn) is the summation of the number...
Polymers
Design Example: Application of Archimedes' Principle
The volume of seawater displaced by the block is determined by first calculating the block's weight. This is done by multiplying the...
Group Design
Hybrid Zones

