The geologic history of seawater oxygen isotopes from marine iron oxides

The oxygen isotope composition (δ¹⁸O) of marine sedimentary rocks has increased by 10 to 15 per mil since Archean time. Interpretation of this trend is hindered by the dual control of temperature and fluid δ¹⁸O on the rocks' isotopic composition. A new δ¹⁸O record in marine iron oxides covering the past ~2000 million years shows a similar secular rise. Iron oxide precipitation experiments reveal a weakly temperature-dependent iron oxide-water oxygen isotope fractionation, suggesting that increasing seawater δ¹⁸O over time was the primary cause of the long-term rise in δ¹⁸O values of marine precipitates. The ¹⁸O enrichment may have been driven by an increase in terrestrial sediment cover, a change in the proportion of high- and low-temperature crustal alteration, or a combination of these and other factors.