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Updated: Jan 20, 2026

Grafting Multiwalled Carbon Nanotubes with Polystyrene to Enable Self-Assembly and Anisotropic Patchiness
Published on: April 1, 2018
Thermal Conductivity Enhancement Derived from Poly(Methyl Methacrylate)-Grafted Carbon Nanotubes in Poly(Methyl
1School of Chemical Engineering & Materials Science, Chung-Ang University, Seoul 156-756, Korea.
Abstract:
This paper presents a method to enhance thermal conductivity using poly(methyl methacrylate)(PMMA), polystyrene(PS) blends, and incorporation of multiwalled carbon nanotubes (MWCNTs). MWCNTs are selectively localized in PMMA phase to improve conductive properties. In addition, Surface of MWCNTs was treated with PMMA to enhance affinity between matrix and filler. PMMA grafting helps filler localization on matrix phase. Composites using two polymers enhanced thermal conductivity by ~11% compared with composites using only PS or PMMA. Also, PMMA grafting on the surface of MWCNTs enhanced thermal conductivity by ~13% compared with samples without PMMA grafting.
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