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Fluorescence of a chiral pentaphene derivative derived from the hexabenzocoronene Motif
Philipp Rietsch1, Jan Soyka, Steffen Brülls
1Institute of Chemistry and Biochemistry, Freie Universität Berlin, Takustraße 3, Berlin, 14195, Germany. siegfried.eigler@fu-berlin.de.
Abstract:
A new fluorescent pentaphene derivative is presented that differs from hexabenzocoronene (HBC) by one carbon atom in the basal plane skeleton. A 500% increased fluorescence quantum yield is measured compared to the HBC derivative. The pentaphene compound, obtained by a modified Scholl oxidation, is also emissive in the solid-state, due to the packing motif in the crystal.
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