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Metal-Ligand Bonds02:51

Metal-Ligand Bonds

24.0K
The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
24.0K
Ligand Binding Sites02:40

Ligand Binding Sites

14.9K
Proteins are dynamic macromolecules that carry out a wide variety of essential processes; however, the activities of most proteins depend on their interactions with other molecules or ions, known as ligands.
Protein-ligand interactions are quite specific; even though numerous potential ligands surround a cellular protein at any given time, only a particular ligand can bind to that protein. Moreover, a ligand binds only to a dedicated area on the surface of the protein, known as the...
14.9K
Ligand Binding and Linkage00:49

Ligand Binding and Linkage

5.5K
Allosteric proteins have more than one ligand binding site; the binding of a ligand to any of these sites influences the binding of ligands to the other sites. When a protein is allosteric, its binding sites are called coupled or linked.  In the case of enzymes, the site that binds to the substrate is known as the active site and the other site is known as the regulatory site. When a ligand binds to the regulatory site, this leads to conformational changes in the protein that can influence...
5.5K
Metallic Solids02:37

Metallic Solids

20.5K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.5K
Structures of Solids02:22

Structures of Solids

17.5K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
17.5K
Network Covalent Solids02:18

Network Covalent Solids

16.1K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.1K

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Updated: Jan 20, 2026

Production and Characterization of Vacuum Deposited Organic Light Emitting Diodes
07:44

Production and Characterization of Vacuum Deposited Organic Light Emitting Diodes

Published on: November 16, 2018

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Polypyridyl ligands as a versatile platform for solid-state light-emitting devices.

Babak Pashaei1, Soheila Karimi1, Hashem Shahroosvand1

  • 1Group for Molecular Engineering of Advanced Functional Materials (GMA), Department of Chemistry, University of Zanjan, Zanjan, Iran. shahroos@znu.ac.ir.

Chemical Society Reviews
|August 17, 2019
PubMed
Summary

Transition metal complexes are advancing molecular electronics for organic light-emitting diodes (OLEDs) and light-emitting electrochemical cells (LECs). This review details their design, synthesis, and application in efficient, stable light-emitting devices.

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Area of Science:

  • Materials Science
  • Chemistry
  • Physics

Background:

  • Inorganic semiconductors are being replaced by molecule-based compounds for current-to-light conversion.
  • This shift has spurred interdisciplinary collaborations and the development of organic light-emitting diodes (OLEDs) and light-emitting electrochemical cells (LECs).

Purpose of the Study:

  • To review the role of transition metal coordination complexes (TMCs) in advancing molecular electronics for OLEDs and LECs.
  • To highlight the design, synthesis, and application of specific TMCs (Ir(iii), Pt(ii), Cu(i), Ag(i)) as emissive components.
  • To discuss strategies for optimizing emitters and fabricating efficient, stable devices.

Main Methods:

  • Literature review focusing on TMCs for OLEDs and LECs.
  • Analysis of molecular design principles for tuning color and efficiency.
  • Survey of third-generation TMCs exhibiting thermally activated delayed fluorescence (TADF).

Main Results:

  • TMCs, particularly Ir(iii), Pt(ii), Cu(i), and Ag(i) complexes, are crucial for OLED and LEC development.
  • Molecular design involving metal, cyclometalate, and ligands is key to optimizing performance.
  • Third-generation TMCs show promise for high external quantum efficiencies and stability, including TADF emitters.

Conclusions:

  • TMCs have significantly advanced molecular electronics for light-emitting applications.
  • Rational design of TMC-based TADF emitters requires further research to overcome conceptual challenges.
  • Tailor-made TMCs are essential for fabricating next-generation OLEDs and LECs for specific applications.